Four acid-catalysed dehydration reactions proceed without interference

被引：9
作者：
Lirag, Rio Carlo [1 ]
Miljanic, Ognjen S. [1 ]
机构：
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 66期
基金：
美国国家科学基金会;
关键词：
SHOTGUN PROCESS; ESTERIFICATION METHOD; PARALLEL RECOGNITION; SCALENE TRIANGLE; DIFFERENTIATION; LIBRARIES; SYSTEMS;
D O I：
10.1039/c4cc02990a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four acid-catalysed dehydration reactions can proceed in one pot, simultaneously and without interference, to yield one imine, one acetal (or boronic ester), one ester and one alkene, even though many other cross-products could be conceived. This advanced self-sorting behaviour is attributed to different dehydration rates, brought about by dissimilar electronic properties of starting materials.
引用
收藏
页码：9401 / 9404
页数：4
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