Unexpected 1D self-assembly of carbonate-templated sandwich-like macrocycle-based Ag20S10 luminescent nanoclusters

被引：48
作者：
Zhou, Kun [1 ]
Qin, Chao [1 ]
Wang, Xin-Long [1 ]
Shao, Kui-Zhan [1 ]
Yan, Li-Kai [1 ]
Su, Zhong-Min [1 ]
机构：
[1] NE Normal Univ, Fac Chem, Minist Educ, Inst Funct Mat Chem,Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China
来源：
CRYSTENGCOMM | 2014年 / 16卷 / 34期
关键词：
FLEXIBLE SUPRAMOLECULAR SYNTHONS; SILVER(I) COMPLEXES; THERMOCHROMIC-LUMINESCENCE; COORDINATION POLYMERS; CLUSTER COMPLEXES; METAL-COMPLEXES; ALKYNYL CAGE; ANION; LIGANDS; NANOPARTICLES;
D O I：
10.1039/c4ce00867g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first example of 1D self-assembly of carbonate-templated sandwich-like macrocycle-based Ag20S10 nanoclusters, {[(CO32-) @Ag-20((SBu)-Bu-t)(10)(CH3COO)(8)(DMF)(2)]center dot 2H(2)O}(n) (1), is reported. Compound 1 is stable both in the solid state and in solution. It exhibits potential wide gap semiconductor properties, reversible thermochromic luminescence behaviour and excellent electrochemical properties.
引用
收藏
页码：7860 / 7864
页数：5
相关论文
共 78 条
  • [21] A dodecanuclear copper(II) cage self-assembled from six dicopper building units
    Ghosh, Aloke Kumar
    Pait, Moumita
    Clerac, Rodolphe
    Mathoniere, Corine
    Bertolasi, Valerio
    Bauza, Antonio
    Frontera, Antonio
    Pramanik, Kausikisankar
    Ray, Debashis
    [J]. DALTON TRANSACTIONS, 2014, 43 (10) : 4076 - 4085
  • [22] {[Ag42(CO3)(C≡ CtBu)27(CH3CN)2][CoW12O40]2}[BF4]: An Intercluster Sandwich Compound
    Gruber, Franziska
    Jansen, Martin
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (29) : 4924 - 4926
  • [23] Systematic Investigation of Silver-Carbon Bonding in Coordination Frameworks with Aryl Ligands That Contain Ethynyl and Ethenyl Substituents
    Hau, Sam C. K.
    Mak, Thomas C. W.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (17) : 5387 - 5400
  • [24] Enlargement of Globular Silver Alkynide Cluster via Core Transformation
    Hau, Sam C. K.
    Cheng, Ping-Shing
    Mak, Thomas C. W.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (06) : 2922 - 2925
  • [25] Intensely Luminescent Gold(I)-Silver(I) Cluster with Hypercoordinated Carbon
    Jia, Jian-Hua
    Wang, Quan-Ming
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (46) : 16634 - +
  • [26] [Ag70(PW9O34)2(tBuCC)44(H2O)2]8+: ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions
    Jiang, Zhan-Guo
    Shi, Kang
    Lin, Yu-Mei
    Wang, Quan-Ming
    [J]. CHEMICAL COMMUNICATIONS, 2014, 50 (18) : 2353 - 2355
  • [27] NEW ASPECTS OF THE ELECTROCHEMISTRY OF HETEROPOLYACIDS .4. ACIDITY DEPENDENT CYCLIC VOLTAMMETRIC BEHAVIOR OF PHOSPHOTUNGSTIC AND SILICOTUNGSTIC HETEROPOLYANIONS IN WATER AND N,N-DIMETHYLFORMAMIDE
    KEITA, B
    NADJO, L
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 227 (1-2) : 77 - 98
  • [28] Luminescent AgAu Alloy Clusters Derived from Ag Nanoparticles - Manifestations of Tunable AuI-CuI Metallophilic Interactions
    Krishnadas, Kumaranchira R.
    Udayabhaskararao, Thumu
    Choudhury, Susobhan
    Goswami, Nirmal
    Pal, Samir Kumar
    Pradeep, Thalappil
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014 (05) : 908 - 916
  • [29] Lerner H.- W., 2005, CHEM COMMUN, P4545
  • [30] Dihalogen-templated synthesis of dodecanuclear silver dichalcogenophosphate clusters
    Li, Bing
    Liao, Jian-Hong
    Li, Yi-Juan
    Liu, C. W.
    [J]. CRYSTENGCOMM, 2013, 15 (31): : 6140 - 6143
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