Unexpected 1D self-assembly of carbonate-templated sandwich-like macrocycle-based Ag20S10 luminescent nanoclusters

被引：48
作者：
Zhou, Kun [1 ]
Qin, Chao [1 ]
Wang, Xin-Long [1 ]
Shao, Kui-Zhan [1 ]
Yan, Li-Kai [1 ]
Su, Zhong-Min [1 ]
机构：
[1] NE Normal Univ, Fac Chem, Minist Educ, Inst Funct Mat Chem,Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China
来源：
CRYSTENGCOMM | 2014年 / 16卷 / 34期
关键词：
FLEXIBLE SUPRAMOLECULAR SYNTHONS; SILVER(I) COMPLEXES; THERMOCHROMIC-LUMINESCENCE; COORDINATION POLYMERS; CLUSTER COMPLEXES; METAL-COMPLEXES; ALKYNYL CAGE; ANION; LIGANDS; NANOPARTICLES;
D O I：
10.1039/c4ce00867g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first example of 1D self-assembly of carbonate-templated sandwich-like macrocycle-based Ag20S10 nanoclusters, {[(CO32-) @Ag-20((SBu)-Bu-t)(10)(CH3COO)(8)(DMF)(2)]center dot 2H(2)O}(n) (1), is reported. Compound 1 is stable both in the solid state and in solution. It exhibits potential wide gap semiconductor properties, reversible thermochromic luminescence behaviour and excellent electrochemical properties.
引用
收藏
页码：7860 / 7864
页数：5
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