Electrochemical degradation of antibiotic levofloxacin by PbO2 electrode: Kinetics, energy demands and reaction pathways

In this work, the electrochemical degradation of antibiotic levofloxacin (LFX) has been studied using a novel rare earth La, V co-doped PbO2 electrode. The effect of applied current density, pH value and initial LFX concentration on the degradation performance were systematically evaluated. The results demonstrated that electrochemical oxidation of LFX over the La-Y-PbO2 electrode was highly effective and the reaction followed an apparent first-order kinetic model. Considering the degradation efficiency and energy efficiency, the relative optimal conditions are identified as current density 30 mA cm(-2), pH 3 and initial LFX concentration 800 mg L-1. According to the identified products, a reaction mechanism has been proposed and the products were further oxidized to CO2, H2O, NH4-, NO3- and F-. A total of four aromatic intermediate products of LFX degradation were identified and the different structural changes to the LFX molecule included pepiperazinyl hydroxylation, decarboxylation and defluorination. (C) 2018 Elsevier Ltd. All rights reserved.