The confinement effect in zeolites

被引：159

作者：

Sastre, G. ^{[1
]}

Corma, A. ^{[1
]}

机构：

[1] Univ Politecn Valencia, Inst Tecnol Quim, CSIC, Valencia 46022, Spain

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2009年 / 305卷 / 1-2期

关键词：

Confinement; Zeolites; Catalysis; Theory; Orbitals; STRUCTURE-DIRECTING AGENTS; MOLECULAR-SIEVES; TEMPLATING ABILITY; SHAPE SELECTIVITY; CONSTRAINT INDEX; DEPENDENCE; CATALYSIS; SILICALITE; CHEMISTRY; ALUMINOSILICATES;

D O I：

10.1016/j.molcata.2008.10.042

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

As microporous materials, zeolites entrap molecules allowing their diffusion, adsorption and reaction within the channel system. This confinement affects the physico-chemistry Of Such incoming molecules in different ways. Derouane pioneered research onto the confinement effect in zeolites and extracted ideas and conclusions regarding physisorption, catalytic cracking and diffusion. His work on this topic is reviewed in this article and further updates on the confinement effects by other groups are also analysed. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：3 / 7

页数：5

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