Water vapor continuum: Whether collision-induced absorption is involved?

被引:19
作者
Vigasin, A. A. [1 ]
机构
[1] Russian Acad Sci, Obukhov Inst Atmospher Phys, Moscow 119017, Russia
关键词
Water vapor continuum; Collision-induced absorption; Partitioning in phase space; TEMPERATURE-DEPENDENCE; EQUILIBRIUM-CONSTANT; SPECTRAL REGION; PHASE-SPACE; FREE STATES; CM(-1); DIMER; CO2; COMPLEXES; NU(1);
D O I
10.1016/j.jqsrt.2014.06.019
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
In a series of recent publications, the idea is pursued to shed a new light on the theory of the water vapor continuum absorption invoking the mechanism of collision-induced absorption. In the opinion of the present author, a portion of theoretical suggestions on this subject is biased and may thus lead to untenable conclusions about the nature of the continuum. The most typical drawback consists of improper consideration of statistics in the ensemble of interacting monomers that lead to embedding incorrect statistical weights to various types of molecular pairs which can form. The current note aims at clarifying the term "collision-induced absorption" in order to avoid incongruity in understanding the nature of the water vapor continuum. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:58 / 64
页数:7
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