Layered Zn2[Co(CN)6](CH3COO) double metal cyanide: a two-dimensional DMC phase with excellent catalytic performance

被引：26

作者：

Marquez, Carlos ^{[1
]}

Simonov, Arkadiy ^{[2
]}

Wharmby, Michael T. ^{[3
]}

Van Goethem, Cedric ^{[1
]}

Vankelecom, Ivo ^{[1
]}

Bueken, Bart ^{[1
]}

Krajnc, Andraz ^{[4
]}

Mali, Gregor ^{[4
]}

De Vos, Dirk ^{[1
]}

De Baerdemaeker, Trees ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, Celestijnenlaan 200F, B-3001 Leuven, Belgium

[2] Univ Oxford, Inorgan Chem Lab, South Parks Rd, Oxford OX1 3QR, England

[3] Deutsch Elektronen Synchrotron DESY, Notkestr 85, D-22607 Hamburg, Germany

[4] Natl Inst Chem, Dept Inorgan Chem & Technol, Hajdrihova 19, Ljubljana 1001, Slovenia

来源：

CHEMICAL SCIENCE | 2019年 / 10卷 / 18期

关键词：

RING-OPENING POLYMERIZATIONS; HIGHLY-ACTIVE CATALYSTS; PRUSSIAN BLUE ANALOGS; PROPYLENE-OXIDE; ORGANIC FRAMEWORK; HETEROGENEOUS CATALYSTS; POWDER DIFFRACTION; DOUBLE HYDROXIDES; INDUCTION PERIOD; HYDROAMINATION;

D O I：

10.1039/c9sc00527g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Double metal cyanides (DMCs) are well known, industrially applied catalysts for ring opening polymerization reactions. In recent years, they have been studied for a variety of catalytic reactions, as well as other applications, such as energy storage and Cs sorption. Herein, a new, layered DMC phase (L-DMC), Zn-2[Co(CN)(6)](CH3COO)center dot 4H(2)O, was synthesized. The structure, which crystallizes in the monoclinic space group P2(1)/m, consists of positively charged {Zn2Co(CN)(6)}(+) DMC layers linked through acetate groups and presents a new layered structure to the family of double metal cyanides. L-DMC proved to be a reusable and stable catalyst that exhibited a higher activity than the benchmark DMC catalyst in two important applications: hydroamination of phenylacetylene with 4-isopropylaniline and polymerization of 1,2-epoxyhexane.

引用

页码：4868 / 4875

页数：8