Highly diastereoselective TiCl4 mediated addition of (E)-cinnamyl(tributyl)tin to α-keto esters

被引：8

作者：

Basavaiah, D ^{[1
]}

Sreenivasulu, B ^{[1
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 16期

关键词：

allylation; titanium tetrachloride; alpha-keto esters; cinnamyl-(tributyl)tin; diastereoselectivity;

D O I：

10.1016/S0040-4039(02)00417-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly syn-(87-98%) diastereoselective addition of (E)-cinnamyl(tributyl)tin to alpha-keto esters under the influence of titanium tetrachloride. leading to the isolation of pure alkyl syn-2-aryl-2-hydroxy-3-phenylpent-4-enoates in 50-80% yields, is described. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：2987 / 2990

页数：4

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