Chains of (4,4′-bipyridyl)copper(I) bridged by dimolybdate units

被引：0
|
作者：
You, WS [1 ]
Wang, EB [1 ]
Xu, L [1 ]
Hu, CW [1 ]
Luan, GY [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Changchun 130024, Jilin, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2000年 / 56卷
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D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of the title compound, poly[bis[Copper(I)-mu-(4,4'-bipyridyl)-N:N']-mu-dimolybdato-O:O'] O'], [Cu-2(C10H8N2)(2)(Mo2O7](n), consists of (Mo2O7)(2-) units (with the central O atom lying on twofold symmetry axes) and [Cu(4,4'-bipy)](n)(n+) chains (bipy = bipyridyl); the chains are generated by a c-glide-plane operation. The (Mo2O7)(2-) units are covalently bridged to two [Cu(4,4'-bipy)](n)(n+) chains, forming a complex with a bridged double-chain structure. The Cu-O and Cu-N distances are 2.191(3) and 1.933 (3) Angstrom, respectively.
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页码：289 / 290
页数：2
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