Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation

被引：525

作者：

Hull, Jonathan F. ^{[2
]}

Balcells, David ^{[1
]}

Blakemore, James D. ^{[2
]}

Incarvito, Christopher D. ^{[2
]}

Eisenstein, Odile ^{[1
]}

Brudvig, Gary W. ^{[2
]}

Crabtree, Robert H. ^{[2
]}

机构：

[1] Univ Montpellier 2, CNRS 5253, Inst Charles Gerhardt, F-34095 Montpellier, France

[2] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 25期

关键词：

O BOND FORMATION; PHOTOSYSTEM-II; OXYGEN EVOLUTION; FAMILY; DIMER;

D O I：

10.1021/ja901270f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

引用

页码：8730 / +

页数：3

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