Factors affecting the ratio of etythemal UV (UVER) to broadband (G) irradiance were investigated in this study. Data from four solar monitoring sites in Thailand, namely Chiang Mai, Ubon Ratchathani, Nakhon Fathom and Songkhla were used to investigate the UVER/G ratio in response to geometric and atmospheric parameters. These comprised solar zenith angle, aerosol load, total ozone column, precipitable water and clearness index. A modeling scheme was developed to isolate and examine the effect of each individual environmental parameter on the ratio. Results showed that all parameters with the exception of solar zenith angle and clearness index influenced the ratios in a linear manner. These results were also used to develop a semi-empirical model for estimating hourly etythemal UV irradiance. Data from 2009 to 2010 were used to construct the ratio model while validation was performed using etythemal UV irradiance at the above four sites in 2011. The validation results showed reasonable agreement with a root mean square difference of 13.5% and mean bias difference of -0.5%, under all sky conditions and 10.9% and -0.3%, respectively, under cloudless conditions. (C) 2014 Elsevier B.V. All rights reserved.