In situ confinement of free linkers within a stable MOF membrane for highly improved gas separation properties

被引：30
|
作者：
Kang, Zixi [1 ]
Fan, Lili [1 ]
Wang, Sasa [1 ]
Sun, Daofeng [1 ]
Xue, Ming [2 ]
Qiu, Shilun [2 ]
机构：
[1] China Univ Petr East China, Coll Sci, Qingdao 266580, Shandong, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
CRYSTENGCOMM | 2017年 / 19卷 / 12期
基金：
中国国家自然科学基金;
关键词：
FRAMEWORK ZIF-90 MEMBRANE; MOLECULAR-SIEVE MEMBRANE; FUNCTIONALIZATION; FILMS;
D O I：
10.1039/c7ce00102a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A stable MOF membrane with guest molecules encapsulated in the pores by in situ synthesis has been successfully fabricated. The in situ confinement of linkers in the channels of the MOF membrane improves its gas separation properties, which may provide a general method for fine-tuning the pore size of MOF membranes and develop the functional applications of porous MOF materials.
引用
收藏
页码：1601 / 1606
页数：6
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