Characterization of Biodegradable Films Produced from Mixtures of Alginate, Starch and Babassu Fibers

被引:7
作者
da Silva Raposo, Ana Karoliny [1 ]
Paixao, Louryval Coelho [1 ]
Rocha, Adones Almeida [2 ]
Lopes, Ilmar Alves [2 ]
Silva Santos, Gustavo Augusto [2 ]
Correa Ribeiro, Geyse Adriana [3 ]
de Menezes, Alan Silva [4 ]
Barros Filho, Allan Kardec D. [5 ]
Santana, Audirene Amorim [2 ]
机构
[1] Fed Univ Maranhao UFMA, Interdisciplinary Bachelor Sci & Technol, Ave Portugueses 1966, BR-65080805 Sao Luis, Maranhao, Brazil
[2] Fed Univ Maranhao UFMA, Dept Chem Engn, Ave Portugueses 1966, BR-65080805 Sao Luis, Maranhao, Brazil
[3] Fed Univ Maranhao UFMA, Postgrad Dept Chem, Ave Portugueses 1966, BR-65080805 Sao Luis, Maranhao, Brazil
[4] Fed Univ Maranhao UFMA, Dept Phys, Ave Portugueses 1966, BR-65080805 Sao Luis, Maranhao, Brazil
[5] Fed Univ Maranhao UFMA, Fac Eletr Engn, Ave Portugueses 1966, BR-65080805 Sao Luis, Maranhao, Brazil
关键词
Experimental design; babassu coconut mesocarp; babassu coconut epicarp; alginate; LIGNOCELLULOSIC FIBERS; MECHANICAL-PROPERTIES; NANOCOMPOSITE FILMS; ALKALI TREATMENT; CROSS-LINKING; PROTEIN; MORPHOLOGY; GLYCEROL; SORBITOL; POLYMER;
D O I
10.1007/s10924-020-01952-z
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Optimal formulations for polymeric alginate films with added starch from the babassu coconut mesocarp (BCM), fiber removed from the babassu coconut epicarp (BCEF) and glycerol (G), were determined as base materials to manufacture utensils such as biodegradable packaging and shopping bags, these materials were crosslinked with CaCl2. As from an initial physical evaluation, the selected films: formulations 11 (1.5BCM + 0.38BCEF + 0.60G to solutions of 250 mL) and 13 (0.75BCM + 0.38BCEF + 2.48G to solutions of 250 mL), were submitted to a second reticulation step with the fundamental role of improving the mechanical properties. The fibers added to the polymeric matrix had a positive effect in decreasing the solubility during the two reticulation steps. Complementary trials with the selected formulations confirmed that the material showed a low water absorption tendency, a compact microstructure and relatively homogenous fiber distribution. The films obtained after the second reticulation of formulation 13 gave the best results for tensile strength and the elasticity modulus (10.31 +/- 0.96 MPa and 476.13 +/- 30.02 MPa, respectively). The synergetic formulations stipulated showed potential for application in pilot tests, and hence produce a biopolymer with the necessary properties for industrial application.
引用
收藏
页码:1212 / 1226
页数:15
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