Electrochemical polymerization of a new alkoxy-bridged dithieno (3,2-B:2',3'-D) pyrrole derivative

被引：6
作者：
Kivrak, Arif [1 ]
Yildiz, Huseyin Bekir [2 ,3 ]
Gokyer, Selahattin [1 ]
Bezgin Carbas, Buket [4 ,5 ]
机构：
[1] Van Yuzuncu Yil Univ, Fac Sci, Dept Chem, Van, Turkey
[2] Karatay Univ, Dept Mat Sci & Nanotechnol Engn, KTO, Karatay, Konya, Turkey
[3] FELSIM Inc, Biotechnol Res Lab, Selcuklu, Konya, Turkey
[4] Karamanoglu Mehmetbey Univ, Dept Energy Syst Engn, Karaman, Turkey
[5] Karamanoglu Mehmetbey Univ, Conduct Polymers & Energy Applicat Lab, Karaman, Turkey
来源：
TURKISH JOURNAL OF CHEMISTRY | 2018年 / 42卷 / 02期
关键词：
Conjugated polymers; dithieno; (3; 2-B:2'; 3'-D); pyrrole; electrochromism; electrochemistry; optical properties; LOW-BANDGAP; COPOLYMERS; POLYMERS; ACCEPTOR; ADSORPTION;
D O I：
10.3906/kim-1709-33
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel alkoxy-bridged dithieno (3, 2-B:2',3'-D) pyrrole (DTP) derivative was synthesized and its corresponding polymer poly(1,2-bis(2-(4H-dithieno[3,2-b:2',3'-d]pyrrol-4-yl)ethoxy)ethane) (P(DTP-alkoxy-DTP)) was successfully obtained electrochemically. The effects of alkoxy bridge in the structure on the electrochemical and spectroelectro-chemical properties of the polymer were also investigated in detail. The results showed that the polymer film exhibits multielectrochromic behavior and a low band gap of 1.82 eV.
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收藏
页码：439 / +
页数：10
相关论文
共 35 条
  • [1] Synthesis and Characterization of Unsymmetric Indolodithienopyrrole and Extended Diindolodithienopyrrole
    Balaji, Ganapathy
    Phua, Dazril Izrar
    Shim, Wong Low
    Valiyaveettil, Suresh
    [J]. ORGANIC LETTERS, 2010, 12 (02) : 232 - 235
  • [2] BERLIN A, 1992, MAKROMOL CHEM, V193, P399
  • [3] Adsorption of carboxyl-terminated dithiophene and terthiophene molecules on ITO electrodes and their electrochemical coupling to polymer layers. The influence of molecular geometry
    Berlin, A
    Zotti, G
    Schiavon, G
    Zecchin, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (51) : 13453 - 13460
  • [4] New fluorene-xanthene-based hybrid electrochromic and fluorescent polymers via donor-acceptor approach
    Carbas, Buket Bezgin
    Onal, Ahmet M.
    [J]. ELECTROCHIMICA ACTA, 2012, 66 : 38 - 44
  • [5] Electrochemical synthesis of new conducting copolymers containing pseudo-polyether cages with pyrrole
    Cihaner, Atilla
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2007, 605 (01): : 8 - 14
  • [6] Highly Fluorescent Dithieno[3,2-b:2′,3′-d]pyrrole-Based Materials: Synthesis, Characterization, and OLED Device Applications
    Evenson, Sean J.
    Mumm, Matthew J.
    Pokhodnya, Konstantin I.
    Rasmussen, Seth C.
    [J]. MACROMOLECULES, 2011, 44 (04) : 835 - 841
  • [7] N-Acyldithieno[3,2-b:2′,3′-d]pyrroles: Second Generation Dithieno[3,2-b:2′,3′-d]pyrrole Building Blocks with Stabilized Energy Levels
    Evenson, Sean J.
    Rasmussen, Seth C.
    [J]. ORGANIC LETTERS, 2010, 12 (18) : 4054 - 4057
  • [8] Synthesis and characterization of two isomeric dithienopyrrole series and the corresponding electropolymers
    Foertsch, Sebastian
    Baeuerle, Peter
    [J]. POLYMER CHEMISTRY, 2017, 8 (23) : 3586 - 3595
  • [9] Synthesis and electro-optical properties of new conjugated hybrid polymers based on furan and fluorene units
    Gunes, Arzu
    Cihaner, Atilla
    Onal, Ahmet M.
    [J]. ELECTROCHIMICA ACTA, 2013, 89 : 339 - 345
  • [10] Synthesis and Characterization of Poly(Dithieno[3,2-b:2′,3′-d]pyrrole) Derivatives Containing Thiophene Moieties and Their Application to Organic Devices
    Jeong, Hyung-Gu
    Lim, Bogyu
    Na, Seok-In
    Baeg, Kang-Jun
    Kim, Juhwan
    Yun, Jin-Mun
    Kim, Dong-Yu
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2011, 212 (21) : 2308 - 2318
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