Statistical Study of the Influence of CNTs Purification and Plasma Functionalization on the Properties of Polycarbonate-CNTs Nanocomposites

被引:39
作者
Maio, Andrea [1 ]
Botta, Luigi [1 ]
Tito, Alina Carmen [2 ]
Pellegrino, Lorenzo [2 ]
Daghetta, Matteo [2 ]
Scaffaro, Roberto [1 ]
机构
[1] Univ Palermo, Dept Civil, I-90128 Palermo, Italy
[2] Politecn Milan, Dept Chem Mat & Chem Engn Giulio Natta, I-20133 Milan, Italy
关键词
cold plasma; full factorial design; hydrophilic coatings; nanocomposites; optical emission spectroscopy (OES); WALLED CARBON NANOTUBES; ETHANOL OXIDATION REACTION; ELECTROCHEMICAL ENERGY-STORAGE; TUNED SURFACE FUNCTIONALITIES; POLYMER-BASED NANOCOMPOSITES; LARGE-SCALE PURIFICATION; POLYANILINE NANOCOMPOSITES; NEGATIVE PERMITTIVITY; CHEMICAL OXIDATION; FIELD-EMISSION;
D O I
10.1002/ppap.201400008
中图分类号
O59 [应用物理学];
学科分类号
摘要
This work reports a statistical study on the relationship between the chemical-physical properties of CNTs, which vary by changing the conditions of purification and plasma treatment, and the macroscopic properties of PC-based nanocomposites. CNTs are synthesized and then purified in two different ways and used as fillers for the preparation of PC/CNTs nanocomposites. In some cases, oxygen plasma treatment is carried out to improve their affinity to the matrix. The CNTs are characterized by TGA, ICP/OES, and FT-Raman spectroscopy, titration and morphological analysis. Mechanical, dynamic-mechanical, electrical, and morphological tests are used for characterizing PC/CNTs nanocomposites.
引用
收藏
页码:664 / 677
页数:14
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