Crystal structure of [(C5Me4Et)3Rh3(μ3-Se)2](PF6)2CH3CN and [(C5Me4Et)2Rh2(μ2-Cl)3]PF6

被引：7
作者：
Abramov, P. A. [1 ]
Sokolov, M. N. [1 ,2 ]
Virovets, A. V. [1 ]
Fedin, V. P. [1 ,2 ]
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2009年 / 50卷 / 01期
关键词：
rhodium; selenium; clusters; hydrothermal synthesis; X-ray analysis; IRIDIUM COMPLEXES; RHODIUM; LIGANDS;
D O I：
10.1007/s10947-009-0022-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of [(C5Me4Et)(3)Rh-3(mu(3)-Se)(2)](PF6)(2) and [(C5Me4Et)(2)Rh-2(mu(2)-Cl)(3)]PF6, obtained in the reaction of [(C5Me4Et)Rh(C6H6)](PF6)(2) with ZnSe in 4M HCl under hydrothermal conditions, is determined. In agreement with the 18VE rule, the triangular cluster contains single metal-metal bonds (Rh-Rh 2.864(1) A...), whereas they are absent in the binuclear complex (Rh ...Rh 3,216(1) A...).
引用
收藏
页码：162 / 165
页数：4
相关论文
共 50 条
[31]   Modified synthesis of mixed-ligand dinuclear Ru-Ir, Ru-Rh, and Ru-Ru polyhydride-bridged complexes, CpsRuH3ML (Cps = C5Me5 (Cp*), C5tBu3H2 (Cp‡); M = Rh, Ir, Ru; L = C5(CH3)5, C6H6, p-CH3C6H4CH(CH3)2) [J].
Shimogawa, Ryuichi ;
Takao, Toshiro ;
Suzuki, Hiroharu .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 818 :168-178
[32]   Intermediates and action effects in the activation of carbon-fluorine bonds by η5-pentamethylcyclopentadienylrhodium halide complexes;: crystal structure of [{η5-C5Me3[CH2C6F4P(C6F5)CH2]2-1,3}RhBr]+•Br- [J].
Atherton, MJ ;
Fawcett, J ;
Holloway, JH ;
Hope, EG ;
Russell, DR ;
Saunders, GC .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 582 (02) :163-172
[33]   Synthesis and Crystal Structure of [W3S4(Acac)3(PPh3)3]PF6 • 0.5CHCl3 and [W3S4(Hfac)3(PPh3)2Br] • 2CHCl3 [J].
Adonin, S. A. ;
Virovets, A. V. ;
Sokolov, M. N. ;
Fedin, V. P. .
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2010, 36 (10) :734-738
[34]   Double complex salts [Pd(NH3)4]3[Rh(NO2)6]2, [Pd(NH3)4]3[Rh(NO2)6]2·H2O as promising precursors to prepare Pd-Rh nanoalloys [J].
A. A. Rybinskaya ;
P. E. Plyusnin ;
E. A. Bykova ;
S. A. Gromilov ;
Yu. V. Shubin ;
S. V. Korenev .
Journal of Structural Chemistry, 2012, 53 :527-533
[35]   Double complex salts [Pd(NH3)4]3[Rh(NO2)6]2, [Pd(NH3)4]3[Rh(NO2)6]2•H2O as promising precursors to prepare Pd-Rh nanoalloys [J].
Rybinskaya, A. A. ;
Plyusnin, P. E. ;
Bykova, E. A. ;
Gromilov, S. A. ;
Shubin, Yu. V. ;
Korenev, S. V. .
JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 53 (03) :527-533
[36]   Crystal structure of [Rh(H2O)5Cl](C7H7O3S)2 and Cs[Rh(H2O)5NO3](C7H7O3S)3•H2O [J].
Vorobieva, S. N. ;
Baidina, I. A. ;
Belyaev, A. V. ;
Korolkov, I. V. ;
Alferova, N. I. .
JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 56 (08) :1606-1612
[37]   Reactions of [Rh(Tp*)(PPh3)2] (Tp* = hydrotris(3,5-dimethylpyrazolyl)-borate) involving fragmentation or loss of Tp*.: Structures of [Rh(Cl)2(H)(PPh3)2(pz*)], [(PPh3)2Rh(μ-SC6F5)2Rh (SC6F5)(H)(PPh3)(pz*)] (pz*=3,5-dimethylpyrazole) and [{Rh(Cl)2(PPh3)2}2Hg] [J].
Circu, V ;
Fernandes, MA ;
Carlton, L .
POLYHEDRON, 2003, 22 (25-26) :3293-3298
[38]   Crystal structure of [Rh(H2O)5Cl](C7H7O3S)2 and Cs[Rh(H2O)5NO3](C7H7O3S)3•H2O [J].
S. N. Vorobieva ;
I. A. Baidina ;
A. V. Belyaev ;
I. V. Korolkov ;
N. I. Alferova .
Journal of Structural Chemistry, 2015, 56 :1606-1612
[39]   The [Ag{Se2C2(CN)2}(Se6)]3-, [Sb{Se2C2(CN)2}2]3-, and [As(Se)3(CH2CN)]2- anions:: Facile formation of the maleonitrilediselenolate (mns) ligand, [Se2C2(CN)2]2- [J].
Smith, DM ;
Albrecht-Schmitt, TE ;
Ibers, JA .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998, 37 (08) :1089-1091
[40]   Versatile reactivity of dioxaneferrocenylimine palladacycles by controlled acid hydrolysis. Crystal and molecular structure of [Pd{CpFe[η5-C5H2{CH(OMe)2}C(H)=N-2,4,6-Me3C6H2]}(Cl)(PPh2Et)] [J].
Martinez, Javier ;
Marino, Marta ;
Caamano, Marcelo ;
Teresa Pereira, Ma ;
Ortigueira, Juan M. ;
Gayoso, Eduardo ;
Lopez-Torres, Margarita ;
Vila, Jose M. .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 740 :92-97
12345