Crystal structure of [(C5Me4Et)3Rh3(μ3-Se)2](PF6)2CH3CN and [(C5Me4Et)2Rh2(μ2-Cl)3]PF6

被引：7
|
作者：
Abramov, P. A. [1 ]
Sokolov, M. N. [1 ,2 ]
Virovets, A. V. [1 ]
Fedin, V. P. [1 ,2 ]
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2009年 / 50卷 / 01期
关键词：
rhodium; selenium; clusters; hydrothermal synthesis; X-ray analysis; IRIDIUM COMPLEXES; RHODIUM; LIGANDS;
D O I：
10.1007/s10947-009-0022-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of [(C5Me4Et)(3)Rh-3(mu(3)-Se)(2)](PF6)(2) and [(C5Me4Et)(2)Rh-2(mu(2)-Cl)(3)]PF6, obtained in the reaction of [(C5Me4Et)Rh(C6H6)](PF6)(2) with ZnSe in 4M HCl under hydrothermal conditions, is determined. In agreement with the 18VE rule, the triangular cluster contains single metal-metal bonds (Rh-Rh 2.864(1) A...), whereas they are absent in the binuclear complex (Rh ...Rh 3,216(1) A...).
引用
收藏
页码：162 / 165
页数：4
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