Rhodium-Catalyzed Cross-Coupling of Alkenyl Halides with Arylboron Compounds

被引：15

作者：

Matsuda, Takanori ^{[1
]}

Suzuki, Kentaro ^{[1
]}

Miura, Norio ^{[1
]}

机构：

[1] Tokyo Univ Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 17期

关键词：

alkenes; boron; cross-coupling; rhodium; synthetic methods; ALPHA; BETA-UNSATURATED CARBOXYLIC-ACIDS; STEREOSELECTIVE-SYNTHESIS; CINE-SUBSTITUTION; ARYL; ARYLATION; EFFICIENT; REAGENTS; CARBON;

D O I：

10.1002/adsc.201300482

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The rhodium(I)-catalyzed reaction between arylboronic esters and excess 1,2-dichloroethene selectively afforded (2-chlorovinyl)arenes. Double arylation yielding 1,2-diarylethenes was observed when 1,2-dibromoethene was reacted with 2.5 equivalents of arylboronic acid.

引用

页码：3396 / 3400

页数：5

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