A 3D chiral Zn(II) complex based on achiral ligands 2-(1H-imidazolyl-1-methyl)-1H-benzimidazole and adipate

被引：13
作者：
Wang, Xiuxiu [1 ]
Yu, Min [1 ]
Li, Ting [1 ]
Meng, Xiangru [1 ]
机构：
[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 40卷
基金：
中国国家自然科学基金;
关键词：
Zn(II)-complex; Chirality; Thermostability; Fluorescence; METAL-ORGANIC FRAMEWORKS; SPONTANEOUS RESOLUTION; COORDINATION POLYMER; INDUCTION; DESIGN;
D O I：
10.1016/j.inoche.2013.12.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel 3D chiral complex, [Zn(adi)(0.5)(imb)](n) (1) (Himb = 2-(1H-imidazolyl-1-methyl)-1H-benzimidazole, H(2)adi = adipic acid) has been synthesized by solvothermal technique. X-ray diffraction analysis indicates that complex 1 consists of two kinds of channels with left-handed helical chains and one kind of zigzag chains. The channels and chains are connected through sharing Zn(II) centers to generate a 3D chiral complex. The TG analysis shows that complex 1 possesses great thermal stability. The fluorescence property of complex 1 has been measured in the solid-state at room temperature. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：187 / 189
页数：3
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