A tubular-like porous carbon derived from waste American poplar fruit as advanced electrode material for high-performance supercapacitor

被引:86
作者
Kumar, T. Rajesh [1 ]
Senthil, Raja Arumugam [1 ]
Pan, Zhigang [1 ,2 ]
Pan, Junqing [1 ]
Sun, Yanzhi [1 ]
机构
[1] Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, State Key Lab Chem Resources Engn, Coll Chem, Beijing 100029, Peoples R China
[2] Anhui Chilwee Power Ltd, Qingyang 242807, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
American poplar fruit waste; Biomass porous carbon; KOH activation; High specific capacitance; Supercapacitor; ACTIVATED CARBON; FACILE SYNTHESIS; POMELO PEEL; HIGH-ENERGY; BIOMASS; FLOWER; COMPOSITE; LEAVES; NANOSHEETS; FRAMEWORK;
D O I
10.1016/j.est.2020.101903
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Recently, the naturally available biomass wastes are received considerable attention as an appropriate carbon precursor to making low-price, sustainable, and environmental friendly porous carbon for supercapacitors. In this study, we have derived a tubular-like porous carbon (TPC) from natural waste American poplar fruit as a carbon precursor via simple carbonization and KOH activation processes. The derived TPC exhibits an impressive tubular-like framework with extremely arranged porous structures and an enhanced surface area of 942 m(2) g(-1). Besides, the TPC exhibits superior specific capacitance (SC) (423 F g(-1) at 1 A g(-1)) and rate ability (remained 217 F g(-1) of SC still at 200 A g(-1)). It also has very-extensive cyclic life with only loss 3% of SC after 200,000 cycles still at 200 A g(-1). The as-fabricated symmetrical cell under 6 M KOH offered a noteworthy SC of 58.71 F g(-1) at 1 A g(-1), superb specific energy of 7.99 Wh kg(-1) at 372 W kg(-1) as well as outstanding cyclic durability with preserved 80.2% of SC after 10,000 cycles at 10 A g(-1). Meanwhile, the symmetrical cell under 1 M Et4NBF4/AN electrolyte expressed an increased SC of 31.68 F g(-1) at 1 A g(-1), high specific energy 13.75 Wh kg(-1) at 624 W kg(-1) as well as excellent cyclic durability with preserved 60.5% of SC after 10,000 cycles at 10 A g(-1). Thus, the present work recommends that waste American poplar fruit is a sustainable carbon source for production of hierarchical porous carbon for energy storage device applications.
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页数:11
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