Controlling the Growth of Palladium Aerogels with High-Performance toward Bioelectrocatalytic Oxidation of Glucose

被引:127
作者
Wen, Dan [1 ]
Herrmann, Anne-Kristin [1 ]
Borchardt, Lars [1 ]
Simon, Frank [2 ]
Liu, Wei [1 ]
Kaskel, Stefan [1 ]
Eychmueller, Alexander [1 ]
机构
[1] Tech Univ Dresden, D-01062 Dresden, Germany
[2] Leibniz Inst Polymer Res Dresden, D-01069 Dresden, Germany
关键词
DIRECT ELECTRON-TRANSFER; DIRECT ELECTROCHEMISTRY; POROUS-ELECTRODE; BIOFUEL CELLS; GRAPHENE; OXIDASE; NANOPARTICLES; ELECTROCATALYSIS; SEMICONDUCTOR; SENSORS;
D O I
10.1021/ja412062e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the controllable synthesis of Pd aerogels with high surface area and porosity by destabilizing colloidal solutions of Pd nanoparticles with variable concentrations of calcium ions. Enzyme electrodes based on Pd aerogels co-immobilized with glucose oxidase show high activity toward glucose oxidation and are promising materials for applications in bioelectronics.
引用
收藏
页码:2727 / 2730
页数:4
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