BUCKMINSTERFULLERENE CATIONS: NEW DIMENSIONS IN GAS-PHASE ION CHEMISTRY

被引：26
作者：
Bohme, Diethard K. [1 ]
机构：
[1] York Univ, Dept Chem, Ctr Res Mass Spectrometry, Ctr Res Earth & Space Sci, Toronto, ON M3J 1P3, Canada
来源：
MASS SPECTROMETRY REVIEWS | 2009年 / 28卷 / 04期
关键词：
fullerene cations; electron transfer; proton transfer; cation transfer; derivatization; polymerization; interstellar chemistry; BALL-AND-CHAIN; CHARGE-SEPARATION REACTIONS; HIGH-ENERGY COLLISIONS; FULLERENE CATIONS; FLOW TUBE; MOLECULE REACTIONS; PROTON-TRANSFER; C-60(X+) X=1-3; CHEMICAL-IONIZATION; INTERSTELLAR CLOUDS;
D O I：
10.1002/mas.20227
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The author provides a brief overview, and shares the extraordinary excitement, of the years of unprecedented discoveries in ion chemistry that followed the first production of fullerene powder in 1990. Various charge states of the buckminsterfullerene C-60(n+) cation became available by conventional electron-impact ionization of the vapor of this powder and so for mass-spectrometric measurements of ion reactivity. The emphasis here will be on fullerene-ion research performed in the author's own laboratory and York University using electron ionization flow-tube mass spectrometry techniques. (C) 2009 Wiley Periodicals, Inc., Mass Spec Rev 28:672-693, 2009
引用
收藏
页码：672 / 693
页数：22
相关论文
共 95 条
[1]   Fullerene dications and trications as initiators in the gas-phase ''ball-and-chain'' polymerization of allene and propyne: Observation of a remarkable periodicity in chain growth with allene [J].
Baranov, V ;
Wang, JR ;
Javahery, G ;
Petrie, S ;
Hopkinson, AC ;
Bohme, DK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (08) :2040-2049
[2]   Proton elimination in charge-separation reactions with hydrogen halides driven by chemical-bond formation with triply-charged C-60 cations [J].
Baranov, V ;
Bohme, DK .
CHEMICAL PHYSICS LETTERS, 1996, 258 (1-2) :203-206
[3]   Isomer-specific trends with charge state in gas-phase reactions of fullerene cations, C-60(x+) (x=1-3), with nitromethane and methyl nitrite: Polymethoxylation of C-60 dications [J].
Baranov, V ;
Hopkinson, AC ;
Bohme, DK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (30) :7055-7060
[4]   Gas-phase reactions of singly and multiply-charged fullerene cations, C60x+ (x=1-3), with iron pentacarbonyl:: kinetic control by Coulombic barriers [J].
Baranov, V ;
Bohme, DK .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1997, 165 :249-255
[5]   REACTIONS OF FE+ COORDINATED TO THE PI-DONATING LIGANDS C2H4, C-C5H5, C6H6 AND C-60 WITH N2O AND CO - PROBING THE BONDING IN (C-60FE+ [J].
BARANOV, V ;
BOHME, DK .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1995, 149 :543-553
[6]   ION-BEAM STUDIES OF ATOMIC ION COLLISIONS WITH C-60 - CHEMISTRY AT SURFACE, SUBSTITUTIONAL, AND ENDOHEDRAL SITES [J].
BASIR, Y ;
WAN, ZM ;
CHRISTIAN, JF ;
ANDERSON, SL .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1994, 138 :173-185
[7]   INTERACTION OF MN+ AND MN-2(+) WITH C-60 - EXOHEDRAL AND ENDOHEDRAL METAL-FULLERENE BONDING [J].
BASIR, Y ;
ANDERSON, SL .
CHEMICAL PHYSICS LETTERS, 1995, 243 (1-2) :45-48
[8]   The influence of surface strain on the chemical reactivity of fullerene ions: addition reactions with cyclopentadiene and 1,3-cyclohexadiene [J].
Becker, H ;
Scott, LT ;
Bohme, DK .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1997, 167 :519-524
[9]   Extraterrestrial helium trapped in fullerenes in the sudbury impact structure [J].
Becker, L ;
Poreda, RJ ;
Bada, JL .
SCIENCE, 1996, 272 (5259) :249-252
[10]   Impact event at the Permian-Triassic boundary: Evidence from extraterrestrial noble gases in fullerenes [J].
Becker, L ;
Poreda, RJ ;
Hunt, AG ;
Bunch, TE ;
Rampino, M .
SCIENCE, 2001, 291 (5508) :1530-1533
12345678910