Integrating single-wall carbon nanotubes into donor-acceptor nanohybrids

被引：221

作者：

Guldi, DM ^{[1
]}

Rahman, GMA

Jux, N

Tagmatarchis, N

Prato, M

机构：

[1] Univ Erlangen Nurnberg, Inst Phys & Theoret Chem, D-91058 Erlangen, Germany

[2] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA

[3] Univ Erlangen Nurnberg, Inst Organ Chem, D-91058 Erlangen, Germany

[4] Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 41期

关键词：

carbon nanotubes; donor-acceptor systems; electron transfer; porphyrinoids; zinc;

D O I：

10.1002/anie.200461217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A tube for electrons: Through π-π and Coulomb interactions, a complex is obtained between carbon nanotubes grafted with pyrene+ (1) and the zinc porphyrin complex 2. Photoexcitation of the resulting donor-acceptor assembly is followed by a rapid and efficient charge separation to generate a charge-separated state that lives for microseconds.

引用

页码：5526 / 5530

页数：5

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