Facile Synthesis of Molybdenum Disulfide Micro-Spheres and the Tribological Properties in Liquid Paraffin

被引：2
作者：
Shi, Huaqiang [1 ]
Zhou, Xiaodong [1 ]
Zhang, Shaoling [1 ]
Fu, Xun [1 ]
机构：
[1] Qingdao Univ Sci & Technol, Key Lab Ecochem Engn, Minist Educ, Coll Chem & Mol Engn, Qingdao 266042, Shandong, Peoples R China
来源：
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY | 2009年 / 30卷 / 04期
关键词：
Cyanex; 302; extraction-solvothermal method; micro-spheres; MoS2; tribological properties; SOLVOTHERMAL SYNTHESIS; SOLVENT-EXTRACTION; MOS2; NANOPARTICLES; SULFIDES; BEHAVIOR; FLUIDS; WS2;
D O I：
10.1080/01932690802548544
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Well-dispersed MoS2 micro-spheres with the diameters of 0.51.5m have been successfully synthesized via the extraction-solvothermal method. The [image omitted] ions were extracted into hexane by the extractant Cyanex 302 (di-(2,4,4-trimethylpentyl) monothiophosphinic acid) firstly, then the extracted solution was given solvothermal treatment to synthesize MoS2 at 150C for 24hours. The obtained samples was characterized by XRD, EDS, SEM, TEM, and HRTEM technologies, respectively. Results indicated that Cyanex 302 acted as phase transferring agent, reductant, sulfur source and morphology-controlling agent in the whole procedure. Moreover, the tribological properties of liquid paraffin (LP) containing the as-prepared MoS2 micro-spheres were also evaluated on a four-ball machine and the chemical states of some typical elements on the worn surfaces were examined with XPS, showing that the MoS2 product was an excellent oil additive in LP with good anti-wear and friction-reducing properties.
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页码：581 / 586
页数：6
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