Structure and NIR luminescence of lanthanide(III) complexes with an organic tridentate ligand

被引：14

作者：

An, Bao-Li ^{[1
,2
]}

Song, Jian ^{[1
]}

Cheah, Kok-Wai ^{[3
]}

Ren, Yuan-Yuan ^{[1
]}

Cheng, Zhi-Xuan ^{[1
]}

机构：

[1] Shanghai Univ, Dept Chem, Coll Sci, Shanghai 200444, Peoples R China

[2] Shanghai Univ, Key Lab Adv Displayed & Syst Applicat, Shanghai 200072, Peoples R China

[3] Hong Kong Baptist Univ, Dept Phys, Hong Kong, Hong Kong, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 09期

关键词：

X-ray crystallography; Neodymium complex; Erbium complex; Ytterbium complex; Luminescence; IONS;

D O I：

10.1016/j.ica.2009.02.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some lanthanide (Ln) complexes (Ln = Er, Nd, Yb) with an organic ligand, 6-diphenylamine carbonyl 2-pyridine carboxylic acid (HDPAP), have been synthesized. The crystal structure and near infrared luminescence of these complexes (Er-DPAP, Nd-DPAP and Yb-DPAP) have been investigated. The results showed that the lanthanide complexes have electroneutral structures and the near infrared (NIR) emission exhibits characteristic narrow emission of the lanthanide ions. The energy transfer mechanisms in the lanthanide complexes were discussed. (C) 2009 Elsevier B. V. All rights reserved.

引用

页码：3196 / 3200

页数：5

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