Synthesis and Crystal Structure of a Supramolecular Zinc(II) Complex with Salen-Type Bisoxime Ligand

被引：0

作者：

Dong Wen-Kui ^{[1
]}

Tang Xiao-Lu ^{[1
]}

He Xue-Ni ^{[1
]}

Zhao Chun-Yu ^{[1
]}

Yan Hai-Bo ^{[1
]}

Yu Tian-Zhi ^{[2
]}

机构：

[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China

[2] Lanzhou Jiaotong Univ, Key Lab Optoelect Technol & Intelligent Control, Minist Educ, Lanzhou 730070, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 25卷 / 03期

关键词：

4,4 ',6,6 '-tetrachloro-2,2 '-[ethylenedioxybis(nitrilomethylidyne)]diphenol; zinc(II) complex; synthesis; crystal structure; CLUSTER; CU(II);

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A supramolecular zine(II) complex [ZnL(H2O)(2)](n) bearing Salen-type bisoxime chelate ligand 4,4',6,6 '-tetrachloro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol (H2L), has been synthesized and structurally characterized by elemental analyses, IR spectra and X-ray single crystal structure determination. The crystal structure of [ZnL(H2O)(2)] indicates that the complex consists of one zine(II) ion, one L2- unit and two coordinated water molecules. The complex exhibits slightly distorted octahedral geometry with the Salen-type bisoxime ligand forming the basal N2O2 coordination plane and two oxygen atoms from the coordinated water molecules in the axial positions. An infinite ID metal-water chain-like supramolecular structure is formed by intermolecular hydrogen bonds. CCDC: 684104.

引用

页码：528 / 532

页数：5

共 15 条

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