Rapid and green synthesis of phenols catalyzed by a deep eutectic mixture based on fluorinated alcohol in water

被引：21

作者：

Wang, Liang ^{[1
]}

Dai, Dong-yan ^{[1
]}

Chen, Qun ^{[1
]}

He, Ming-yang ^{[1
]}

机构：

[1] Changzhou Univ, Sch Petrochem Engn, Changzhou 213164, Peoples R China

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2014年 / 158卷

基金：

中国国家自然科学基金;

关键词：

Deep eutectic mixture; Hexafluoroisopropanol; Aryl/heteroaryl boronic acids; Phenols; ARYLBORONIC ACIDS; HYDROXYLATION; EFFICIENT; PEROXIDE; ETHERS; METAL; MILD;

D O I：

10.1016/j.jfluchem.2013.12.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new deep eutectic mixture based on choline chloride and 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) was prepared and was found to be effective for the rapid transformation of aryl/heteroaryl boronic acids to the corresponding phenols in water using hydrogen peroxide as the oxidant. Broad substrate compatibility, metal- and additive-free conditions as well as reusability of the catalyst made this procedure more environmentally benign. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：44 / +

页数：4

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