Rapid and green synthesis of phenols catalyzed by a deep eutectic mixture based on fluorinated alcohol in water

被引：21
作者：
Wang, Liang [1 ]
Dai, Dong-yan [1 ]
Chen, Qun [1 ]
He, Ming-yang [1 ]
机构：
[1] Changzhou Univ, Sch Petrochem Engn, Changzhou 213164, Peoples R China
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2014年 / 158卷
基金：
中国国家自然科学基金;
关键词：
Deep eutectic mixture; Hexafluoroisopropanol; Aryl/heteroaryl boronic acids; Phenols; ARYLBORONIC ACIDS; HYDROXYLATION; EFFICIENT; PEROXIDE; ETHERS; METAL; MILD;
D O I：
10.1016/j.jfluchem.2013.12.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new deep eutectic mixture based on choline chloride and 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) was prepared and was found to be effective for the rapid transformation of aryl/heteroaryl boronic acids to the corresponding phenols in water using hydrogen peroxide as the oxidant. Broad substrate compatibility, metal- and additive-free conditions as well as reusability of the catalyst made this procedure more environmentally benign. (C) 2013 Elsevier B.V. All rights reserved.
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收藏
页码：44 / +
页数：4
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