Densities and Viscosities for Binary Liquid Mixtures of n-Undecane+1-Heptanol, 1-Octanol, 1-Nonanol, and 1-Decanol from 283.15 to 363.15 K at 0.1 MPa

被引:32
作者
Guzman-Lopez, Adriana [1 ]
Iglesias-Silva, Gustavo A. [1 ]
Reyes-Garcia, Fatima [1 ]
Estrada-Baltazar, Alejandro [1 ]
Ramos-Estrada, Mariana [2 ]
机构
[1] Inst Tecnol Celaya, Dept Ingn Quim, Celaya 38010, Guanajuato, Mexico
[2] Univ Michoacana, Fac Ingn Quim, Morelia 58030, Michoacan, Mexico
关键词
EXCESS MOLAR VOLUMES; N-ALCOHOLS; 1-ALKANOLS; OCTANE; DECANE; 80-DEGREES-C; TEMPERATURES; 15-DEGREES-C; COEFFICIENTS; PRESSURES;
D O I
10.1021/acs.jced.6b00834
中图分类号
O414.1 [热力学];
学科分类号
摘要
This paper presents densities and viscosities of binary mixtures of n-undecane with 1-alcohols with carbon atoms from C-7 to C10 from 283.15 to 363.15 K at 0.1 MPa. Densities are measured using a vibrating tube densimeter, while viscosities are from a pellet microviscometer. Excess molar volumes and viscosity deviations are calculated from the experimental data. The excess molar volumes present positive deviations for the binary mixtures with 1-heptanol, 1-octanol, and 1-nonanol. The excess molar volumes of n-undecane + 1-decanol present negative deviations at lower temperatures. The viscosity deviations show negative deviations from ideality over the entire temperature range. Also we present a correlation for the kinematic viscosity based upon the activation Gibbs energy.
引用
收藏
页码:780 / 795
页数:16
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