A new experimental method for a fast and reliable quantification of saturates, aromatics, resins, and asphaltenes in crude oils

被引:20
作者
Rezaee, Sara [1 ]
Tavakkoli, Mohammad [1 ]
Doherty, Rocio [1 ]
Vargas, Francisco M. [1 ]
机构
[1] Rice Univ, Dept Chem & Biomol Engn, Houston, TX 77005 USA
关键词
ASTM method; chromatography column; crude oil; fractionation; SARA analysis; SARA FRACTIONS; SEPARATION;
D O I
10.1080/10916466.2020.1790598
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The complexity of the crude oil makes its compositional characterization a very challenging task. As a conventional way to characterize crude oil, SARA fractionation is based on the differences between the solubility and polarity of the four fractions: Saturates, Aromatics, Resins, and Asphaltenes. In this study, we present an improved method for SARA analysis: clay/alumina chromatography method. This method is three to four times faster compared to ASTM D2007 method and requires less solvent. The proposed system is practical for industrial application since the equipment is fairly inexpensive and could be easily assembled in any laboratory.
引用
收藏
页码:955 / 961
页数:7
相关论文
共 20 条
[1]   Sensitivity of asphaltene properties to separation techniques [J].
Alboudwarej, H ;
Beck, J ;
Svrcek, WY ;
Yarranton, HW ;
Akbarzadeh, K .
ENERGY & FUELS, 2002, 16 (02) :462-469
[2]  
[Anonymous], 2002, THESIS
[3]  
[Anonymous], 2005, D65602005 ASTM
[4]  
[Anonymous], 2007, D20072007 ASTM
[5]   Determination of saturate, aromatic, resin, and asphaltenic (SARA) components in crude oils by means of infrared and near-infrared spectroscopy [J].
Aske, N ;
Kallevik, H ;
Sjöblom, J .
ENERGY & FUELS, 2001, 15 (05) :1304-1312
[6]   Efficient and Quick Method for Saturates, Aromatics, Resins, and Asphaltenes Analysis of Whole Crude Oil by Thin-Layer Chromatography-Flame Ionization Detector [J].
Bisht, Harender ;
Reddy, Manasa ;
Malvanker, Manthan ;
Patil, Rahul C. ;
Gupta, Ajay ;
Hazarika, Bibeka ;
Das, Asit K. .
ENERGY & FUELS, 2013, 27 (06) :3006-3013
[7]   Group-type characterization of crude oil and bitumen. Part I: Enhanced separation and quantification of saturates, aromatics, resins and asphaltenes (SARA) [J].
Bissada, K. K. ;
Tan, Jingqiang ;
Szymczyk, Ewa ;
Darnell, Mike ;
Mei, Mei .
ORGANIC GEOCHEMISTRY, 2016, 95 :21-28
[8]  
Fan T., 2002, EVALUATING CRUDE OIL, DOI DOI 10.2118/75228-MS
[9]   Rapid and accurate SARA analysis of medium gravity crude oils [J].
Fan, TG ;
Buckley, JS .
ENERGY & FUELS, 2002, 16 (06) :1571-1575
[10]  
Hansen C.M., 2007, Hansen's Solubility Parameters: A User's Handbook, DOI [10.1201/9781420006834, DOI 10.1201/9781420006834]