Molecular Doping Enhances Photoconductivity in Polymer Bulk Heterojunction Solar Cells

被引：178

作者：

Zhang, Yuan ^{[1
]}

Zhou, Huiqiong ^{[2
]}

Seifter, Jason ^{[2
]}

Ying, Lei ^{[1
]}

Mikhailovsky, Alexander ^{[1
]}

Heeger, Alan J. ^{[2
]}

Bazan, Guillermo C. ^{[1
]}

Nguyen, Thuc-Quyen ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

[2] Univ Calif Santa Barbara, Dept Phys, Santa Barbara, CA 93106 USA

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 48期

关键词：

molecular doping; F4-TCNQ; photocurrent; charge carrier density; charge recombination; PHOTOVOLTAIC CELLS; CONJUGATED POLYMER; CHARGE-TRANSPORT; PHASE-SEPARATION; BAND-GAP; EFFICIENCY; FILMS; MORPHOLOGY; PHOTOCURRENT; PERFORMANCE;

D O I：

10.1002/adma.201302159

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of low concentrations (<1:100, dopant:donor) of a fluorinated p-type dopant, F4-TCNQ leads to a considerable enhancement of the photocurrent in PCDTBT:PC70BM bulk heterojunction solar cells. As a result, the power conversion efficiency increases from 6.41% to 7.94 %. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7038 / 7044

页数：7

共 51 条

[21] A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene: fullerene solar cells [J].

Kim, Y ;

Cook, S ;

Tuladhar, SM ;

Choulis, SA ;

Nelson, J ;

Durrant, JR ;

Bradley, DDC ;

Giles, M ;

Mcculloch, I ;

Ha, CS ;

Ree, M .

NATURE MATERIALS, 2006, 5 (03) :197-203

[22] Light intensity dependence of open-circuit voltage of polymer:fullerene solar cells -: art. no. 123509 [J].

Koster, LJA ;

Mihailetchi, VD ;

Ramaker, R ;

Blom, PWM .

APPLIED PHYSICS LETTERS, 2005, 86 (12) :1-3

[23] Plasmon-Enhanced Charge Carrier Generation in Organic Photovoltaic Films Using Silver Nanoprisms [J].

Kulkarni, Abhishek P. ;

Noone, Kevin M. ;

Munechika, Keiko ;

Guyer, Samuel R. ;

Ginger, David S. .

NANO LETTERS, 2010, 10 (04) :1501-1505

[24] Band Bending in Conjugated Polymer Layers [J].

Lange, Ilja ;

Blakesley, James C. ;

Frisch, Johannes ;

Vollmer, Antje ;

Koch, Norbert ;

Neher, Dieter .

PHYSICAL REVIEW LETTERS, 2011, 106 (21)

[25] High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends [J].

Li, G ;

Shrotriya, V ;

Huang, JS ;

Yao, Y ;

Moriarty, T ;

Emery, K ;

Yang, Y .

NATURE MATERIALS, 2005, 4 (11) :864-868

[26] Post-Deposition Treatment of an Arylated-Carbazole Conjugated Polymer for Solar Cell Fabrication [J].

Liu, Xiaofeng ;

Wen, Wen ;

Bazan, Guillermo C. .

ADVANCED MATERIALS, 2012, 24 (33) :4505-4510

[27] Effect of traps on the performance of bulk heterojunction organic solar cells [J].

Mandoc, M. M. ;

Kooistra, F. B. ;

Hummelen, J. C. ;

de Boer, B. ;

Blom, P. W. M. .

APPLIED PHYSICS LETTERS, 2007, 91 (26)

[28] Space-charge limited photocurrent [J].

Mihailetchi, VD ;

Wildeman, J ;

Blom, PWM .

PHYSICAL REVIEW LETTERS, 2005, 94 (12)

[29] Charge transport and photocurrent generation in poly (3-hexylthiophene): Methanofullerene bulk-heterojunction solar cells [J].

Mihailetchi, VD ;

Xie, HX ;

de Boer, B ;

Koster, LJA ;

Blom, PWM .

ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (05) :699-708

[30] Charge carrier formation in polythiophene/fullerene blend films studied by transient absorption spectroscopy [J].

Ohkita, Hideo ;

Cook, Steffan ;

Astuti, Yeni ;

Duffy, Warren ;

Tierney, Steve ;

Zhang, Weimin ;

Heeney, Martin ;

McCulloch, Iain ;

Nelson, Jenny ;

Bradley, Donal D. C. ;

Durrant, James R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (10) :3030-3042

← 1 2 3 4 5 6 →