Molecular Doping Enhances Photoconductivity in Polymer Bulk Heterojunction Solar Cells

被引：178

作者：

Zhang, Yuan ^{[1
]}

Zhou, Huiqiong ^{[2
]}

Seifter, Jason ^{[2
]}

Ying, Lei ^{[1
]}

Mikhailovsky, Alexander ^{[1
]}

Heeger, Alan J. ^{[2
]}

Bazan, Guillermo C. ^{[1
]}

Nguyen, Thuc-Quyen ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

[2] Univ Calif Santa Barbara, Dept Phys, Santa Barbara, CA 93106 USA

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 48期

关键词：

molecular doping; F4-TCNQ; photocurrent; charge carrier density; charge recombination; PHOTOVOLTAIC CELLS; CONJUGATED POLYMER; CHARGE-TRANSPORT; PHASE-SEPARATION; BAND-GAP; EFFICIENCY; FILMS; MORPHOLOGY; PHOTOCURRENT; PERFORMANCE;

D O I：

10.1002/adma.201302159

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of low concentrations (<1:100, dopant:donor) of a fluorinated p-type dopant, F4-TCNQ leads to a considerable enhancement of the photocurrent in PCDTBT:PC70BM bulk heterojunction solar cells. As a result, the power conversion efficiency increases from 6.41% to 7.94 %. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7038 / 7044

页数：7

共 51 条

[1] Exciton Formation, Relaxation, and Decay in PCDTBT [J].

Banerji, Natalie ;

Cowan, Sarah ;

Leclerc, Mario ;

Vauthey, Eric ;

Heeger, Alan J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (49) :17459-17470

[2] Device physics of polymer:fullerene bulk heterojunction solar cells [J].

Blom, Paul W. M. ;

Mihailetchi, Valentin D. ;

Koster, L. Jan Anton ;

Markov, Denis E. .

ADVANCED MATERIALS, 2007, 19 (12) :1551-1566

[3] Toward a rational design of poly(2,7-carbazole) derivatives for solar cells [J].

Blouin, Nicolas ;

Michaud, Alexandre ;

Gendron, David ;

Wakim, Salem ;

Blair, Emily ;

Neagu-Plesu, Rodica ;

Belletete, Michel ;

Durocher, Gilles ;

Tao, Ye ;

Leclerc, Mario .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (02) :732-742

[4] Charge Photogeneration in Organic Solar Cells [J].

Clarke, Tracey M. ;

Durrant, James R. .

CHEMICAL REVIEWS, 2010, 110 (11) :6736-6767

[5] 7,7,8,8-Tetracyanoquinodimethane-Based Molecular Dopants for p-Type Doping of OLEDs: A Theoretical Investigation [J].

Cosimbescu, Lelia ;

Padmaperuma, Asanga B. ;

Gaspar, Daniel J. .

JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (46) :13498-13503

[6] Recombination in polymer-fullerene bulk heterojunction solar cells [J].

Cowan, Sarah R. ;

Roy, Anshuman ;

Heeger, Alan J. .

PHYSICAL REVIEW B, 2010, 82 (24)

[7] Reduced Charge Transfer Exciton Recombination in Organic Semiconductor Heterojunctions by Molecular Doping [J].

Deschler, Felix ;

Da Como, Enrico ;

Limmer, Thomas ;

Tautz, Raphael ;

Godde, Tillmann ;

Bayer, Manfred ;

von Hauff, Elizabeth ;

Yilmaz, Seyfullah ;

Allard, Sybille ;

Scherf, Ullrich ;

Feldmann, Jochen .

PHYSICAL REVIEW LETTERS, 2011, 107 (12)

[8] MIP-type organic solar cells incorporating phthalocyanine/fullerene mixed layers and doped wide-gap transport layers [J].

Drechsel, J ;

Männig, B ;

Gebeyehu, D ;

Pfeiffer, M ;

Leo, K ;

Hoppe, H .

ORGANIC ELECTRONICS, 2004, 5 (04) :175-186

[9] Controlled p-doping of zinc phthalocyanine by coevaporation with tetrafluorotetracyanoquinodimethane:: A direct and inverse photoemission study [J].

Gao, WY ;

Kahn, A .

APPLIED PHYSICS LETTERS, 2001, 79 (24) :4040-4042

[10]

Grancini G, 2013, NAT MATER, V12, P29, DOI [10.1038/nmat3502, 10.1038/NMAT3502]

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