Synthesis, structure and characterization of new 1D and 2D Ni(II) coordination polymers

被引：6
|
作者：
Wang, Jingyuan [1 ]
Zhang, Yu [1 ]
Ji, Yanyan [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
SOLID STATE SCIENCES | 2009年 / 11卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Self-penetrating network; Coordination polymer; Crystal structure; Polyrotaxane; NETWORK SOLIDS; FRAMEWORKS; CHEMISTRY;
D O I：
10.1016/j.solidstatesciences.2008.06.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new Ni(II) coordination polymers, namely [Ni(3)(Hsdac)(2)(sdac)(2)(2,2'-biPY)(2)] (1) and [Ni(2)(sdac)(2)(4,4'biPY)(2)]center dot 2H(2)O (2) (sdba = 4,4'-sulfonyldibenzoate, 2,2'-bipy = 2,2'-bipyridine, 4,4'-bipy = 4,4'-bipyridine), have been prepared under hydrothermal conditions and characterized by single crystal X-ray diffraction analyses. Compound I possesses an interesting chain structure. Adjacent chains are further linked through H-bond interactions between Hsdac ligands to give a two-dimensional (2D) supramolecular architecture. Compound 2 displays an unusual 2D polyrotaxane-like network. (C) 2008 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码：364 / 367
页数：4
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