Synthesis, structure and characterization of new 1D and 2D Ni(II) coordination polymers

被引：6

作者：

Wang, Jingyuan ^{[1
]}

Zhang, Yu ^{[1
]}

Ji, Yanyan ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

SOLID STATE SCIENCES | 2009年 / 11卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Self-penetrating network; Coordination polymer; Crystal structure; Polyrotaxane; NETWORK SOLIDS; FRAMEWORKS; CHEMISTRY;

D O I：

10.1016/j.solidstatesciences.2008.06.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new Ni(II) coordination polymers, namely [Ni(3)(Hsdac)(2)(sdac)(2)(2,2'-biPY)(2)] (1) and [Ni(2)(sdac)(2)(4,4'biPY)(2)]center dot 2H(2)O (2) (sdba = 4,4'-sulfonyldibenzoate, 2,2'-bipy = 2,2'-bipyridine, 4,4'-bipy = 4,4'-bipyridine), have been prepared under hydrothermal conditions and characterized by single crystal X-ray diffraction analyses. Compound I possesses an interesting chain structure. Adjacent chains are further linked through H-bond interactions between Hsdac ligands to give a two-dimensional (2D) supramolecular architecture. Compound 2 displays an unusual 2D polyrotaxane-like network. (C) 2008 Elsevier Masson SAS. All rights reserved.

引用

页码：364 / 367

页数：4

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