Postmetalation ligand modification on the periphery of a diruthenium compound: Toward novel metallayne scaffoldings

被引：31
作者：
Chen, WZ
Ren, T [1 ]
机构：
[1] Univ Miami, Dept Chem, Coral Gables, FL 33146 USA
[2] Univ Miami, Ctr Supramol Sci, Coral Gables, FL 33146 USA
来源：
ORGANOMETALLICS | 2004年 / 23卷 / 16期
关键词：
D O I：
10.1021/om049702d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A diruthenium compound bearing a peripheral iodo substituent cross-couples with acetylenes under Sonogashira conditions to yield a novel family of diruthenium compounds bearing a peripheral alkyne functionality, which can be further functionalized at the axial positions via a reaction with lithiated butadiynyl.
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收藏
页码：3766 / 3768
页数：3
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