Oxidation of hydrocarbons in a barrier discharge reactor

被引：24

作者：

Kudryashov, SV ^{[1
]}

Shchegoleva, GS ^{[1
]}

Sirotkina, EE ^{[1
]}

Ryabov, AY ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petr Chem, Siberian Div, Tomsk 634055, Russia

来源：

HIGH ENERGY CHEMISTRY | 2000年 / 34卷 / 02期

关键词：

Cyclohexanone; Cumene; Barrier Discharge; High Energy Chemistry; Discharge Zone;

D O I：

10.1007/BF02761839

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of n-hexane, cyclohexane, cumene (isopropylbenzene), and cyclohexene in a barrier discharge reactor under conditions ensuring effective product transport out of the discharge zone was studied. It was shown that hydrocarbon oxidation reactions can be carried out in barrier discharge plasma reactors with a fairly high selectivity. The oxidation of n-hexane, cyclohexane, and cumene primarily yields the hydroxy and carbonyl compounds alcohols, aldehydes and ketones. The major product of cyclohexene oxidation is epoxy-cyclohexane (similar to 62 wt %).

引用

页码：112 / 115

页数：4

共 13 条

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