Comparison of an ordered mesoporous aluminosilicate, silica, alumina, titania and zirconia in normal-phase high-performance liquid chromatography

被引：225
作者：
Grun, M
Kurganov, AA
Schacht, S
Schuth, F
Unger, KK
机构：
[1] UNIV MAINZ,INST ANORGAN & ANALYT CHEM,D-55099 MAINZ,GERMANY
[2] UNIV FRANKFURT,INST ANORGAN CHEM,D-60439 FRANKFURT,GERMANY
来源：
JOURNAL OF CHROMATOGRAPHY A | 1996年 / 740卷 / 01期
关键词：
stationary phases; LC; silica; zirconia; aluminosilicate; alumina; titania; MCM-41;
D O I：
10.1016/0021-9673(96)00205-1
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
This paper investigates the behaviour of silica, alumina, titania, zirconia and the novel mesoporous aluminosilicate MCM-41 in normal-phase high-performance liquid chromatography under comparable conditions. The physicochemical properties of the oxides and MCM-41 are described. MCM-41 is an ordered mesoporous material with a regular pore structure composed of an assembly of hexagonal tubes with a pore diameter of 4 nm. In chromatography MCM-41 exhibits acid and basic properties and proves to be suitable for the separation of acid, neutral and basic compounds.
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页码：1 / 9
页数：9
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