Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide

被引：98
作者：
Wang, Chuan [1 ]
Yamamoto, Hisashi [1 ,2 ]
机构：
[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA
[2] Chubu Univ, Mol Catalyst Res Ctr, Kasugai, Aichi 4878501, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 04期
基金：
美国国家卫生研究院;
关键词：
ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; ENANTIOSELECTIVE EPOXIDATION; HYDROXAMIC ACIDS; VANADIUM; COMPLEXES; ALKENES; OLEFINS; MOLYBDENUM(VI); OXIDATION; LIGANDS;
D O I：
10.1021/ja411379e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple, efficient, and environmentally friendly asymmetric epoxidation of primary, secondary, tertiary allylic, and homoallylic alcohols has been accomplished. This process was promoted by a tungsten-bishydroxamic acid complex at room temperature with the use of aqueous 30% H2O2 as oxidant, yielding the products in 84-98% ee.
引用
收藏
页码：1222 / 1225
页数：4
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