Lanthanide-based hexa-nuclear complexes and their use as molecular precursors

被引：48

作者：

Calvez, Guillaume ^{[1
]}

Le Natur, Francois ^{[1
,2
]}

Daiguebonne, Carole ^{[1
]}

Bernot, Kevin ^{[1
]}

Suffren, Yan ^{[1
]}

Guillou, Olivier ^{[1
]}

机构：

[1] INSA Rennes, UMR 6226, Inst Sci Chim Rennes, 20 Ave Buttes de Coesmes, F-35708 Rennes, France

[2] Olnica SAS, 40 Rue Bignon, F-35135 Chantepie, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2017年 / 340卷

关键词：

Hexa-nuclear complexes; Coordination compounds; Molecular precursor; Crystal structures; Photophysical properties; METAL-ORGANIC-FRAMEWORKS; SECONDARY BUILDING UNITS; EARTH BASIC NITRATES; COORDINATION POLYMERS; STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURES; HYDROXIDE COMPLEXES; MAGNET BEHAVIOR; CUBANE-LIKE; PORE-SIZE;

D O I：

10.1016/j.ccr.2016.12.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of lanthanide-based poly-nuclear complexes as molecular precursor for the design of extended molecular frameworks is still an innovative synthesis strategy. Oxo-hydroxo poly-nuclear complexes are generally obtained by controlling pH conditions during reaction process. After a short description of the lanthanide hydrolysis phenomenon and a non-exhaustive inventory of existing complexes with increasing nuclearity, the present review focuses on lanthanide-based hexa-nuclear oxo-hydroxo complexes. Their syntheses and crystal structures are described and their interest as building blocks for the design of new coordination compounds with unprecedented physical properties is highlighted. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：134 / 153

页数：20

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