2-Chloro-6-hydroxypyridinium chloride hydrate

被引：6

作者：

Freytag, M ^{[1
]}

Jones, PG ^{[1
]}

机构：

[1] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270199008045

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, C5H5ClNO+.Cl-.H2O, shows typical features of pyridinium cations (i.e, wider angles at nitrogen and narrower angles at C-2 and C-6 than in unprotonated pyridines). Short C-Cl and C-O bonds may indicate mesomeric stabilization of the positive charge at the N atom. The extended structure involves classical hydrogen bonds of forms N-H ... Cl-, O-hydroxy-H ... O-water and O-water-H ... Cl-. Short Cl ... Cl contacts of 3.3460 (8)Angstrom are also observed. Secondary interactions link anions and cations to form a three-dimensional packing pattern.

引用

页码：1682 / 1685

页数：4

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