Carbodiimides as catalysts for the reduction of CO2 with boranes

被引：34

作者：

Ramos, Alberto ^{[1
]}

Antinolo, Antonio ^{[1
]}

Carrillo-Hermosilla, Fernando ^{[1
]}

Fernandez-Galan, Rafael ^{[1
]}

Rodriguez-Dieguez, Antonio ^{[2
]}

Garcia-Vivo, Daniel ^{[3
]}

机构：

[1] Univ Castilla La Mancha, Fac Ciencias & Tecnol Quim, Dept Quim Inorgan Organ & Bioquim, Campus Univ, E-13071 Ciudad Real, Spain

[2] Univ Granada, Fac Ciencias, Dept Quim Inorgan, Ave Fuente Nueva S-N, E-18071 Granada, Spain

[3] Univ Oviedo, Dept Quim Organ & Inorgan IUQOEM, E-33071 Oviedo, Spain

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 37期

关键词：

FRUSTRATED LEWIS PAIRS; METAL-FREE REDUCTION; CARBON-DIOXIDE; METHANOL; HYDROGENATION; HYDROBORATION; ACTIVATION; TRANSFORMATION; GUANIDINES; CHEMISTRY;

D O I：

10.1039/c8cc02139b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbodiimides catalyse the reduction of CO2 with H-BBN or BH3 center dot SMe2 to give either mixtures of CH2(OBBN)(2) and CH3OBBN or (MeOBO)(3) and B(OMe)(3) under mild conditions (25-60 degrees C, 1 atm CO2). Stoichiometric reactions and theoretical calculations were performed to unveil the mechanism of these catalytic processes.

引用

页码：4700 / 4703

页数：4

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