Non-linear PEG-based thermoresponsive polymer systems

被引：142

作者：

Badi, Nezha ^{[1
,2
]}

机构：

[1] Univ Strasbourg, Inst Charles Sadron, UPR22, CNRS, 23 Rue Laess,BP 84047, F-67034 Strasbourg 2, France

[2] Univ Ghent, Dept Organ & Macromol Chem, Polymer Chem Res Grp, Krijgslaan 281 S4 Bis, B-9000 Ghent, Belgium

来源：

PROGRESS IN POLYMER SCIENCE | 2017年 / 66卷

关键词：

Thermoresponsive polymers; LCST; UCST; Poly(ethylene glycol) derivatives; Smart materials; TRANSFER RADICAL POLYMERIZATION; OLIGO(ETHYLENE GLYCOL) METHACRYLATE; METHYL-ETHER METHACRYLATE; CRITICAL SOLUTION TEMPERATURE; AMPHIPHILIC BLOCK-COPOLYMERS; DILUTE AQUEOUS-SOLUTIONS; LIVING CATIONIC-POLYMERIZATION; CROSS-LINKED MICELLES; BIOCOMPATIBLE MAGNETITE NANOPARTICLES; THERMOSENSITIVE DIBLOCK COPOLYMERS;

D O I：

10.1016/j.progpolymsci.2016.12.006

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(ethylene glycol) (PEG) is one of the most used polymers in medical and biological applications. Its non-toxicity, non-immunogenicity, biocompatibility and solubility in a wide range of solvents offer various possibilities of utilization and explain the amount of studies dealing with this polymer. More recently, non-linear PEG-based monomers attracted much interest due to their thermal behavior. The present review aims at presenting many PEG-based thermoresponsive systems from structural and synthesis point of view and at highlighting all their fascinating properties from their behavior in solution, the fine-tuning of the transition temperature until the formation of smart materials. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：54 / 79

页数：26

共 471 条

[21]

Banerjee P, 2000, J BIOMED MATER RES, V50, P331, DOI 10.1002/(SICI)1097-4636(20000605)50:3<331::AID-JBM6>3.3.CO

[22]

2-K

[23] Morphing Hydrogel Patterns by Thermo-Reversible Fluorescence Switching [J].

Bat, Erhan ;

Lin, En-Wei ;

Saxer, Sina ;

Maynard, Heather D. .

MACROMOLECULAR RAPID COMMUNICATIONS, 2014, 35 (14) :1260-1265

[24] Stimuli-responsive polymers and their applications in drug delivery [J].

Bawa, Priya ;

Pillay, Viness ;

Choonara, Yahya E. ;

du Toit, Lisa C. .

BIOMEDICAL MATERIALS, 2009, 4 (02)

[25] Thermoresponsive behaviour of poly[(oligo(ethyleneglycol methacrylate)]s and their protein conjugates: importance of concentration and solvent system [J].

Bebis, Konstantinos ;

Jones, Mathew W. ;

Haddleton, David M. ;

Gibson, Matthew I. .

POLYMER CHEMISTRY, 2011, 2 (04) :975-982

[26] Libraries of Methacrylic Acid and Oligo(ethylene glycol) Methacrylate Copolymers with LCST Behavior [J].

Becer, C. Remzi ;

Hahn, Sabine ;

Fijten, Martin W. M. ;

Thijs, Hanneke M. L. ;

Hoogenboom, Richard ;

Schubert, Ulrich S. .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (21) :7138-7147

[27] Metal-Free Synthesis of Responsive Polymers: Cloud Point Tuning by Controlled "Click" Reaction [J].

Becer, C. Remzi ;

Kokado, Kenta ;

Weber, Christine ;

Can, Aydin ;

Chujo, Yoshiki ;

Schubert, Ulrich S. .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (06) :1278-1286

[28] Solvent Effects on ATRP of Oligo(ethylene glycol) Methacrylate. Exploring the Limits of Control [J].

Bergenudd, Helena ;

Coullerez, Geraldine ;

Jonsson, Mats ;

Malmstrom, Eva .

MACROMOLECULES, 2009, 42 (09) :3302-3308

[29] Hybrid nanogels by encapsulation of lanthanide-doped LaF3 nanoparticles as elemental tags for detection by atomic mass spectrometry [J].

Berger, Sebastian ;

Ornatsky, Olga ;

Baranov, Vladimir ;

Winnik, Mitchell A. ;

Pich, Andrij .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (24) :5141-5150

[30] Associative graft copolymers comprising a poly(N-isopropylacrylamide) backbone and end-functionalized polyoxyethylene side chains.: Synthesis and aqueous solution properties [J].

Berlinova, IV ;

Dimitrov, IV ;

Vladimirov, NG ;

Samichkov, V ;

Ivanov, Y .

POLYMER, 2001, 42 (14) :5963-5971

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