Non-linear PEG-based thermoresponsive polymer systems

被引:142
作者
Badi, Nezha [1 ,2 ]
机构
[1] Univ Strasbourg, Inst Charles Sadron, UPR22, CNRS, 23 Rue Laess,BP 84047, F-67034 Strasbourg 2, France
[2] Univ Ghent, Dept Organ & Macromol Chem, Polymer Chem Res Grp, Krijgslaan 281 S4 Bis, B-9000 Ghent, Belgium
关键词
Thermoresponsive polymers; LCST; UCST; Poly(ethylene glycol) derivatives; Smart materials; TRANSFER RADICAL POLYMERIZATION; OLIGO(ETHYLENE GLYCOL) METHACRYLATE; METHYL-ETHER METHACRYLATE; CRITICAL SOLUTION TEMPERATURE; AMPHIPHILIC BLOCK-COPOLYMERS; DILUTE AQUEOUS-SOLUTIONS; LIVING CATIONIC-POLYMERIZATION; CROSS-LINKED MICELLES; BIOCOMPATIBLE MAGNETITE NANOPARTICLES; THERMOSENSITIVE DIBLOCK COPOLYMERS;
D O I
10.1016/j.progpolymsci.2016.12.006
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly(ethylene glycol) (PEG) is one of the most used polymers in medical and biological applications. Its non-toxicity, non-immunogenicity, biocompatibility and solubility in a wide range of solvents offer various possibilities of utilization and explain the amount of studies dealing with this polymer. More recently, non-linear PEG-based monomers attracted much interest due to their thermal behavior. The present review aims at presenting many PEG-based thermoresponsive systems from structural and synthesis point of view and at highlighting all their fascinating properties from their behavior in solution, the fine-tuning of the transition temperature until the formation of smart materials. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:54 / 79
页数:26
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