Assembly of Ring-Shaped Phosphorus within Carbon Nanotube Nanoreactors

被引：62

作者：

Zhang, Jinying ^{[1
]}

Zhao, Dan ^{[1
]}

Xiao, Dingbin ^{[1
]}

Ma, Chuansheng ^{[2
,3
]}

Du, Hongchu ^{[4
]}

Li, Xin ^{[1
]}

Zhang, Lihui ^{[1
]}

Huang, Jialiang ^{[1
]}

Huang, Hongyang ^{[1
]}

Jia, Chun-Lin ^{[2
,3
,4
]}

Tomanek, David ^{[5
]}

Niu, Chunming ^{[1
]}

机构：

[1] Xi An Jiao Tong Univ, Ctr Nanomat Renewable Energy, State Key Lab Elect Insulat & Power Equipment, Sch Elect Engn, Xian 710049, Shaanxi, Peoples R China

[2] Xi An Jiao Tong Univ, Sch Elect & Informat Engn, Xian 710049, Shaanxi, Peoples R China

[3] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Shaanxi, Peoples R China

[4] Forschungszentrum Julich, Ernst Ruska Ctr Microscopy & Spect Electrons, D-52425 Julich, Germany

[5] Michigan State Univ, Dept Phys & Astron, E Lansing, MI 48824 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 07期

基金：

中国国家自然科学基金;

关键词：

allotropes; carbon nanotubes; nanoreactors; phosphorus; vapor-phase reactions; LAYER BLACK PHOSPHORUS; CRYSTAL-STRUCTURE; EXFOLIATION; GRAPHENE; SPECTROSCOPY; SULFUR; OXYGEN; PHASE; RED;

D O I：

10.1002/anie.201611740

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A phosphorus allotrope that has not been observed so far, ring-shaped phosphorus consisting of alternate P-8 and P-2 structural units, has been assembled inside multi-walled carbon nanotube nanoreactors with inner diameters of 5-8nm by a chemical vapor transport and reaction of red phosphorus at 500 degrees C. The ring-shaped nanostructures with surrounding graphene walls are stable under ambient conditions. The nanostructures were characterized by high-resolution transmission electron microscopy, scanning transmission electron microscopy, energy-dispersive X-ray spectroscopy, Raman scattering, attenuated total reflectance Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy.

引用

页码：1850 / 1854

页数：5

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