Synthesis and structure of donor-ligand-stabilized tris(cyclopentadienyl)zirconium cations

被引：62

作者：

Brackemeyer, T ^{[1
]}

Erker, G ^{[1
]}

Frohlich, R ^{[1
]}

机构：

[1] UNIV MUNSTER, INST ORGAN CHEM, D-48149 MUNSTER, GERMANY

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 04期

关键词：

D O I：

10.1021/om960777u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of Cp(2)Zr(Cl)CH3 (6) with;sodium cyclopentadienide gives Cp(3)ZrCH(3) (7). Its reaction with dimethylanilinium tetraphenylborate yields the Cp(3)Zr(THF)(+) cation. [CP3Zr+CH3B(C6F5)(3)(-)] (9) is generated by treatment of 7 with tris(pentafluorophenyl)borate. Nitriles add to 9 to form the ligand-stabilized tris(eta 5-cyclopentadienyl)zirconium cation systems Cp(3)Zr(N=CR)(+). With tert-butyl isocyanide, 9 is transformed to yield the donor-ligand-stabilized [Cp(3)Zr(C=NCMe)(3)(CH3B)-C-+(C3F5)(3)(-)] salt 12. Carbon monoxide adds to 9 to give the cationic metal carbonyl complex [Cp(3)Zr(CO)(CH3B)-C-+(C6F5)(3)(-)] (13). Both cation complexes 12 and 13 were characterized by X-ray diffraction.

引用

页码：531 / 536

页数：6

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