Synthesis of benzene from methane and carbon monoxide over silica-supported Rh, Ru and Pd catalysts

被引：7
作者：
Naito, S
Karaki, T
Iritani, T
机构：
[1] Department of Applied Chemistry, Faculty of Engineering, Kanagawa University, 3-27-1, Rokkakubashi, Kanagawa-ku
来源：
CHEMISTRY LETTERS | 1997年 / 09期
关键词：
D O I：
10.1246/cl.1997.877
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Benzene was formed selectively among hydrocarbons produced in CH4-CO reaction over silica supported Rh, Ru and Pd catalysts at 573-723 K under atmospheric pressures, although CO2 was the main product, which was formed jy the disproportionation of CO. Addition of H-2 to CH4-CO reaction accelerated the rate of benzene formation several times, and the selectivity increased considerably.
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页码：877 / 878
页数：2
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