Ion-Size-Dependent Formation of Mixed Titanium/Lanthanide Oxo Clusters

被引：25

作者：

Artner, Christine ^{[1
]}

Kronister, Stefan ^{[1
]}

Czakler, Matthias ^{[1
]}

Schubert, Ulrich ^{[1
]}

机构：

[1] Vienna Univ Technol, Inst Mat Chem, A-1060 Vienna, Austria

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 32期

基金：

奥地利科学基金会;

关键词：

Cluster compounds; Lanthanides; Titanium; Carboxylate ligands; POLYMERS; ALKOXIDE;

D O I：

10.1002/ejic.201402670

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mixed-metal oxo clusters LnTi(4)O(3)(OiPr)(2)(OMc)(11) (Ln = La, Ce; OMc = methacrylate), Ln(2)Ti(6)O(6)(OMc)(18)(HOiPr) (Ln = La, Ce, Nd, Sm) and Ln(2)Ti(4)O(4)(OMc)(14)(HOMc)(2) (Ln = Sm, Eu, Gd, Ho) have been synthesized from titanium isopropoxide, the corresponding lanthanide acetate and methacrylic acid. The type of cluster obtained strongly depends on the size of the lanthanide ion.

引用

页码：5596 / 5602

页数：7

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