Anodic synthesis of a conducting polymer deriving from m-methoxytoluene

被引：13

作者：

Bergaoui, S ^{[1
]}

Saïd, AH ^{[1
]}

Matoussi, F ^{[1
]}

机构：

[1] Fac Sci, Dept Chim, Monastir 5000, Tunisia

来源：

EUROPEAN POLYMER JOURNAL | 2002年 / 38卷 / 09期

关键词：

m-methoxytoluene; electron transfer; conducting polymer; photoluminescence;

D O I：

10.1016/S0014-3057(02)00075-7

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The electropolymerization of in-methoxytoluene is studied in acetonitrile on a platinum anode. In the voltammetric study, a growing film of polymer is deposited on the electrode when sweeping the potential repetitively about the anodic peak. The modified electrode remains conducting after several cycles. Furthermore, in the chronoamperometric analysis, an oscillating current is observed. In the preparative electrolysis, two types of polymer are obtained, the first is soluble and the second is a deposit. insoluble in most usual solvents. Both give very similar results in IR and NMR spectroscopic analysis, which are in agreement with meta-linked aromatic rings. The polymer is photoluminescent and has maximum emission peaks situated in the near IR region. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1731 / 1738

页数：8

共 18 条

[1] FLUORESCENCE PROPERTIES OF HETEROCYCLIC AROMATIC DIETHER DERIVATIVES AND THEIR POLYMERS [J].