Bis(2-aminobenzothiazole-kN)dichlorocobalt(II)

被引:3
作者
Bati, Humeyra
Yuksektepe, Cigdem [1 ]
Caliskan, Nezihe
Buyukgungor, Orhan
机构
[1] Ondokuz Mayis Univ, Art & Sci Fac, Dept Phys, TR-55139 Samsun, Turkey
[2] Ondokuz Mayis Univ, Art & Sci Fac, Dept Chem, TR-55139 Samsun, Turkey
关键词
D O I
10.1107/S1600536806033496
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [CoCl2(C7H6N2S) 2], the Co atom has a slightly distorted tetrahedral coordination geometry, involving two Cl atoms and two N atoms from the thiazole unit [Co-Cl = 2.2435 (8) and 2.2476 (8) angstrom, and Co-N=2.0252 (18) and 2.0308 (17) angstrom]. The interplanar angle between the two benzothiazole groups is 76.44 (4)degrees. The amino groups, acting as donor, partipate in intra- and intermolecular N-H center dot center dot center dot Cl hydrogen bonds, with N center dot center dot center dot Cl distances in the range 3.244 (2)-3.302 (2) angstrom. There are also intermolecular pi-pi, N-H center dot center dot center dot pi and C-H center dot center dot center dot pi interactions in the crystal structure.
引用
收藏
页码:M2313 / M2315
页数:3
相关论文
共 13 条
[1]   Diacetatobis(2-aminobenzothiazole-κN)cobalt(II) [J].
Bati, H ;
Saraçoglu, H ;
Çaliskan, N ;
Soylu, S .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 (07) :M342-M343
[3]  
Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI DOI 10.1107/S0021889899006020
[4]  
Goldfarb RH, 1999, ANTICANCER RES, V19, P1663
[5]  
Karlin K.D., 1986, BIOL INORGANIC COPPE
[6]   trans-Bis(2-amino-6-nitro-1,3-benzo-thiazole-N)dichloroplatinum(II)tetrakis(N,N′-dimethylformamide) solvate and tetrakis(2-amino-5-methyl-1,3,4-thiadiazole-N4)platinum(II) hexachloroplatinate(IV) bis(N,N′-dimethylformamide) solvate [J].
Lynch, DE ;
Duckhouse, HL .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2001, 57 :1036-1038
[7]  
Nadkarni AB, 2000, INDIAN J HETEROCY CH, V9, P309
[8]   Dichloro[2,2-diphenyl-4,4,6,6-tetrakis(3,5-dimethyl-pyrazol-1-yl)cyclotriphosphazene]cobalt(II) [J].
Prabakaran, P ;
Thomas, KRJ ;
Muthiah, PT ;
Bocelli, G ;
Righhi, L .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2001, 57 :m399-m401
[9]   Synthesis and microbiological activity of some novel 5-benzamido- and 5-phenylacetamido- substituted 2-phenylbenzoxazole derivatives [J].
Sener, EA ;
Arpaci, ÖT ;
Yalçin, I ;
Altanlar, N .
FARMACO, 2000, 55 (05) :397-405
[10]  
Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR