Synthesis of porous Cu-BTC with ultrasonic treatment: Effects of ultrasonic power and solvent condition

被引：57
作者：
Israr, Farrukh [1 ]
Kim, Duk Kyung [2 ]
Kim, Yeongmin [1 ]
Oh, Seung Jin [3 ]
Ng, Kim Choon [3 ]
Chun, Wongee [1 ]
机构：
[1] Jeju Natl Univ, Dept Nucl & Energy Engn, Jeju 690756, South Korea
[2] Auburn Univ, Dept Chem, Montgomery, AL 36117 USA
[3] Natl Univ Singapore, Dept Mech Engn, Singapore 117576, Singapore
来源：
ULTRASONICS SONOCHEMISTRY | 2016年 / 29卷
基金：
新加坡国家研究基金会;
关键词：
Cu-BTC; Ultrasonic power effect; Different solvent conditions; METAL-ORGANIC FRAMEWORKS; MICROWAVE SYNTHESIS; HYDROGEN STORAGE; CU-3(BTC)(2); SEPARATION; TEREPHTHALATE; EFFICIENT; MOFS; ADSORPTION;
D O I：
10.1016/j.ultsonch.2015.08.023
中图分类号：
O42 [声学];
学科分类号：
070206 ; 082403 ;
摘要：
Cu-BTC (BTC = 1,3,5-benzenetricarboxylate) metal organic framework (MOF) was synthesized using different solvent conditions with ultrasonic treatment. Solvent mixtures of water/N,N-dimethylformamide (DMF), water/ethanol were used for the reactions with or without a variety of bases under 20 kHz ultrasonically treated conditions. Prepared crystals were purified through 30 min of sonication to remove unreacted chemicals. Treatment time and ultrasonic power effects were compared to get optimum synthetic condition. The characterization of MOF powders was performed by scanning electron microscopy, X-ray powder diffraction, infrared-spectroscopy, thermo-gravimetric analysis and specific surface determination using the BET method. Isolated crystal yields varied with different solvent and applied ultrasonic power conditions. A high isolated crystal yield of 86% was obtained from water/ethanol/DMF solvent system after 120 mm of ultrasonic treatment at 40% power of 750 W. Different solvent conditions led to the formation of Cu-BTC with different surface area, and an extremely high surface area of 1430 m(2)/g was obtained from the crystals taken with the solvent condition of water:DMF = 70:30. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：186 / 193
页数：8
相关论文
共 45 条
  • [1] Probing the Lewis acidity and catalytic activity of the metal-organic framework [Cu3(btc)2] (BTC = benzene-1,3,5-tricarboxylate)
    Alaerts, Luc
    Seguin, Etienne
    Poelman, Hilde
    Thibault-Starzyk, Frederic
    Jacobs, Pierre A.
    De Vos, Dirk E.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (28) : 7353 - 7363
  • [2] Microwave assisted hydrothermal synthesis of a novel CuI-sulfate-pyrazine MOF
    Amo-Ochoa, Pilar
    Givaja, Gonzalo
    Miguel, Pablo J. Sanz
    Castillo, Oscar
    Zamora, Felix
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (08) : 921 - 924
  • [3] High yield 1-L scale synthesis of ZIF-8 via a sonochemical route
    Cho, Hye-Young
    Kim, Jun
    Kim, Se-Na
    Ahn, Wha-Seung
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2013, 169 : 180 - 184
  • [4] Choi JY, 2006, B KOREAN CHEM SOC, V27, P1523
  • [5] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n
    Chui, SSY
    Lo, SMF
    Charmant, JPH
    Orpen, AG
    Williams, ID
    [J]. SCIENCE, 1999, 283 (5405) : 1148 - 1150
  • [6] Hybrid porous solids:: past, present, future
    Ferey, Gerard
    [J]. CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) : 191 - 214
  • [7] Flynn H.G., 1964, PHYS ACOUSTICS, V1, P57
  • [8] Garay AL, 2007, CHEM SOC REV, V36, P846, DOI 10.1039/b600363j
  • [9] Microwave Synthesis of SAPO-11 and AIPO-11: Aspects of Reactor Engineering
    Gharibeh, Murad
    Tompsett, Geoffrey. A.
    Conner, William Curtis
    Yngvesson, K. Sigfrid
    [J]. CHEMPHYSCHEM, 2008, 9 (17) : 2580 - 2591
  • [10] Synthesis of a Metal-Organic Framework Material, Iron Terephthalate, by Ultrasound, Microwave, and Conventional Electric Heating: A Kinetic Study
    Haque, Enamul
    Khan, Nazmul Abedin
    Park, Jung Hwa
    Jhung, Sung Hwa
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (03) : 1046 - 1052
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