PMMA-g-SOY as a sustainable novel dielectric material

被引:33
作者
Thakur, Vijay Kumar [1 ]
Thunga, Mahendra [2 ]
Madbouly, Samy A. [2 ,3 ]
Kessler, Michael R. [1 ]
机构
[1] Washington State Univ, Sch Mech & Mat Engn, Pullman, WA 99164 USA
[2] Iowa State Univ, Dept Mat Sci & Engn, Ames, IA USA
[3] Cairo Univ, Fac Sci, Dept Chem, Giza, Egypt
来源
RSC ADVANCES | 2014年 / 4卷 / 35期
关键词
HIGH-PERMITTIVITY; POLYMER NANOCOMPOSITES; GRAFT-COPOLYMERS; ENERGY-STORAGE; COMPOSITES; NANOTUBES; DESIGN; FIBERS; FLOUR; FILMS;
D O I
10.1039/c4ra01894j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Soy protein (and associated carbohydrate) (SOY) is graft copolymerized with poly(methyl methacrylate) (PMMA) to synthesize novel low cost dielectric materials for multifunctional applications. Graft copolymerization of methyl methacrylate onto pre-activated SOY is carried out using a simple reflux method to form covalently bonded PMMA-g-SOY copolymers. The resulting PMMA-g-SOY is processed into films without employing any toxic chemical solvents. The PMMA-g-SOY films exhibited enhanced storage modulus and a low loss tangent together with promising dielectric properties compared to the pristine PMMA polymer. This strategy may open a new avenue to efficiently use green co-products for multifunctional applications in traditional and structural capacitors.
引用
收藏
页码:18240 / 18249
页数:10
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